1,4-Diformil-2,3,5,6-Tetramitratopiperazine: A New Explosive Based on Glioxal
	Категория: Естественные науки » Химические науки
		Автор: K. Karaghiosoff et al. Издательство: Propellants, Explos., Pyrotech Год издания: 2003 Количество страниц: 6 Язык: русский Формат: PDF Размер: 0 Мб Каталожный номер: 23996	In the present work we describe synthesis and properties of 1,4-diformyl-2,3,5,6-tetranitratopiperazine. The 1,4-diformyl-2,3,5,6- tetranitratopiperazine turned out to be a powerful highly energetic compound. Its physical and chemical properties were investigated by theoretical as well as experimental methods. The detonation energy of 1,4-diformyl-2,3,5,6-tetranitratopiperazine was determined to 5376 kJ/kg or 93% compared to HMX. Molecular and crystal structure of 1,4-diformyl-2,3,5,6-tetranitratopiperazine was elucidated by single crystal X-ray diffraction analysis. An interesting feature of the title substance, its rotamer equilibrium, was investigated by 2D NMR methods.
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	100 Опубликовал: ponkratov1 | 27-08-2009, 00:00 | Просмотров: 916   Комментарии (1)  Печать